Upconversion emission of BaTiO3 : Er nanocrystals

Here, we report the dopant concentration and pump-power dependence upconversion emission properties of erbium doped BaTiO3 nanocrystals derived from sol–emulsion–gel method. Green (550 nm) and red (670 nm) upconversion emissions were observed at room temperature from the 4 S3/2 and 4 F9/2 levels of Er 3+ : BaTiO3 nanocrystals. It is found that at 850 mW of cw excitation power (at 980 nm) the total luminescence was 17130 Cd/m 2 for 1000°C heated 0⋅25 mol% Er-doped BaTiO3 nanocrystals. It is worthwhile to mention that the unusual power-dependent upconversion luminescence (saturation) is observed at higher dopant concentration (2⋅5 mol%) and high pump power. Our analysis confirms that the depletion of the excited state is responsible for the relevant fluorescence upconversion. We have again confirmed that a twophoton excited state absorption process occurs for all samples.